Thermochemical modification of beech wood with ammonium hydroxide

Abstract

Four variants of the thermochemical modification were conducted on beech wood at a temperature of 130 °C, employing NH4OH concentrations of 5% or 10% for durations of either 12 or 24 h. The weight% gain (WPG) and bulking coefficient (BC) were initially calculated. Subsequently, the wood’s degree of discoloration was assessed using the CIELAB-colour-system. Chemical structure alterations were determined through Fourier transform infrared spectroscopy (FTIR), while the compressive strength of the wood parallel to the grain was measured. As the NH4OH concentration increased and the treatment duration extended, the samples displayed simultaneous weight increase and volume reduction. The ΔE* values of the samples ranged from 19.33 to 21.09 units, indicating significant color alteration. FTIR analysis revealed differences between the spectra of the unmodified control sample and the NH4OH-treated samples. The modification reduced in hydroxyl and carboxyl groups within the main and side chains of hemicelluloses. Additionally, a decrease in the absorption peak intensity of the unconjugated carbonyl group at 1740 cm− 1 indicated a relative reduction in hemicellulose content. Compressive strength tests showed that the thermochemical modification improved the modulus of elasticity, increasing it from 10,898 MPa (in the control sample) to a range of 11,663 − 13,390 MPa. Similarly, the compressive strength increased from 77.10 MPa to 81.56-107.19 MPa. Interestingly, this improvement was more pronounced with higher concentrations of NH4OH and prolonged modification durations.