Abstract
Abstract The unconventional solution model of Mobile Order, which has previously been shown to provide a very accurate thermodynamic description of anthracene and pyrene solubilities in binary hydrocarbon+alcohol and alcohol+alcohol solvent mixtures, is extended to aqueous-alcohol solvent systems. An expression is derived for predicting the solubility of an inert crystalline solute in binary alcohol+water mixtures from measured solubilities in both neat liquid solvents plus hydrogen-bonding stability constants. Applications and limitations of the newly-derived equation are assessed using published solubility for 4-chlorobiphenyl dissolved in binary methanol+water, ethanol+water and 1-propanol+water solvent mixtures.
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