Thermoacoustic parametric instability of premixed ammonia flames propagating downwards in an open-closed tube

Abstract

This work investigates the self-excited thermoacoustic parametric instability of downward propagating laminar premixed ammonia flames in an open-closed combustion tube. NH3/O2/N2 flames were propagated at different laminar burning velocities at equivalence ratios of ɸ = 0.8 and ɸ = 1.2. Different unstable flame regimes were observed through pressure fluctuation measurements and synchronized high-speed imaging capturing the lateral and longitudinal perspectives of flame propagation. The observed propagation speed of quasi-planar flames showed a strong correlation with the calculated laminar burning velocities of NH3/O2/N2 mixtures. For the first time, the cellular structures of laminar premixed ammonia flames at the onset of parametric instability were clearly observed from the present experimental approach. The experimental cellular flame wavenumbers and acoustic velocity fluctuation amplitudes at the onset of parametric instability are in qualitative agreement with the theory of stability of laminar flames under acoustic excitation. Experiments have shown that NH3/O2/N2 flames are more unstable than CH4/O2/N2 flames at the same laminar burning velocity independent of Lewis number within the range of tested conditions. The influence of activation energy on parametric instability is investigated through a comparative thermoacoustic analysis between two different fuels at varied equivalence ratios. Ammonia flames are characterized by large overall activation energy and Zeldovich numbers compared to hydrocarbon flames. This work elucidates how this unique property characterizes the acoustic instability of downward propagating premixed ammonia flames in a tube based on classical theories on acoustic instability of laminar premixed flames.