Abstract
AbstractThe new complex PdIPh(tmeda) (1) (tmeda = Me2N(CH2)2NMe2) was prepared by oxidative addition of iodobenzene to {bis(dibenzylideneacetone)}palladium(0) in the presence of tmeda and has been characterized by NMR spectroscopy and X‐ray crystallography. Treatment with MeLi affords the remarkably stable mixed diorgano species PdMePh(tmeda) (2). Both (1) and (2) are useful precursors to other organopalladium species by ligand exchange reactions.
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