Abstract
Poly(2-vinyl-4,4-dimethyl-2-oxazolin-5-one) was used to prepare three-dimensional networks using bisphenol crosslinkers. Among the bisphenols considered, only bisphenols containing electron-withdrawing groups at the site para to the phenol hydroxyls crosslink the polymer. The bisphenol 4,4'-(perfluorobutanediyl-1,4-disulfonyl)diphenol was found to facilitate the reverse reaction in high-boiling solvents, reforming linear polymers at temperatures below the degradation temperature of the linear polymer.
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