Abstract

AbstractThe wide‐spread treatment of thermally activated unpinning of dislocations from point obstacles in terms of the absolute rate theory is criticized. In particular, doubts are raised about the validity of the assumption that a thermodynamic equilibrium distribution is established between the equilibrium state of a pinned dislocation and its saddle‐point configuration. In analogy to Rice's dynamical theory of diffusion an alternative approach to dislocation unpinning is suggested, which does not make use of this assumption and which furthermore accounts for unpinning transitions by‐passing the saddle‐point configuration.

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