Abstract
To investigate the influence of intramolecular charge transfer (CT) characteristics, rigidity, and polarity of a molecule on photophysical properties, we designed and synthesized two types of thermally activated delayed fluorescence (TADF) emitters with malononitrile and acrylonitrile moieties as electron accepting units. Their photophysical properties such as singlet–triplet energy split (ΔEST), photoluminescence quantum yields (PLQYs), and electronic structures were theoretically and experimentally evaluated. Among the synthesized materials, the emitters with an acrylonitrile moiety as an acceptor and phenoxazine, dimethylacridine, and tert-butylcarbazole as a donor revealed small ΔEST values, good PLQYs, and efficient TADF performances. In contrast, the malononitrile derivatives demonstrated high ΔEST values, very low PLQYs, and relatively poor TADF performances even though they have strong intramolecular CT characteristics and high polarity. We found that high molecular polarity and strong intramolecular CT characteristics are not essential factors for attaining good TADF performances over molecular rigidity.
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