Abstract

Rare earth trifluoromethanesulfonate complexes with dimethylsulfoxide (DMSO), [Ln(DMSO) 7.5](CF 3SO 3) 3, Ln ≡ La — Lu, Y, have been prepared and the thermal behaviour studied by TG and DSC techniques. The ligands are lost in two or three steps up to ~540 K. The salt decomposition occurred at temperatures between 620 and 740 K, giving rise to lanthanide fluorides.

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