Abstract
Silver(I) complexes with triethylphosphine and perfluorinated carboxylic acids residues of general formula [Et 3PAgOOCR] 2, where R=C 2F 5, C 3F 7, C 6F 13, C 7F 15, C 8F 17, C 9F 19, C 6F 5 and Et 3PAgOOC(CF 2) 3COOAgPEt 3, were synthesized. Thermal decomposition proceeded in two stages – both exothermic processes corresponding to the elimination of carboxylate and triethylphosphine residues. The final product of the thermal decomposition was metallic silver. Analyses by 13C, 19F, 31P NMR spectroscopy and vibrational spectra suggest trigonal coordination of Ag(I), the coordination sphere consisting of unidentate triethylphosphine and bidentate carboxylates forming bridges between metal ions.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
