Thermal stability, Judd–Ofelt theory analysis and spectroscopic properties of a new Er 3+/Yb 3+-codoped germano-tellurite glass

Abstract

The Er 3+/Yb 3+-codoped 70TeO 2–5Li 2O–10B 2O 3–15GeO 2 glass was prepared. The thermal stability, absorption spectra, emission spectra and up-conversion spectra were measured and investigated. The Judd–Ofelt analysis based on absorption spectra was performed in order to determine the Judd–Ofelt intensity parameters Ω t ( t = 2, 4, 6), spontaneous emission probability, radiative lifetime and branching ratios of several Er 3+ transitions. It was found that this studied glass has good thermal stability, broad fluorescence full width at half maximum (FWHM), large stimulated emission cross-section and strong up-conversion emissions at about 532, 546 and 659 nm, corresponding to the 2H 11/2 → 4I 15/2, 4S 3/2 → 4I 15/2 and 4F 9/2 → 4I 15/2 transitions of Er 3+, respectively under the excitation at 970 nm. The results suggest that this Er 3+/Yb 3+-codoped germano-tellurite glass may be a potentially useful material for developing potential amplifiers and up-conversion optical devices.