Abstract
The durability of PEM fuel cell materials is essential to application longevity. This research explores the limits of thermal stability of platinum/Vulcan XC 72 catalysts and a 46 wt % Pt/Vulcan XC 72/Nafion catalyst layer. The thermal stability of Pt/Vulcan XC 72 catalysts and the PEM fuel cell catalyst layer is studied by thermal gravimetric analysis (TGA) in air. The products of decomposition are analyzed with TGA coupled with mass spectrometry (TGA−MS). Low temperature (100−200 °C) carbon combustion in the presence of platinum is confirmed. The high precision and sensitivity of TGA allows differentiation of two oxidative/mass loss regimes for 46% Pt/C. The presence of surface protective groups raises the activation energy for the low-temperature/low-conversion (≤5%) oxidation of 46% Pt/Vulcan XC 72 (197 ± 13 kJ/mol) compared to a higher temperature/higher conversion level (10−30%) process (140 ± 10 kJ/mol). In PEM fuel cell catalyst layers, the thermal decomposition temperature of Nafion is lowered by...
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