Abstract
Gold nanorods are prepared in aqueous solution by an electrochemical method and are shape controlled by using capping micelles as described by Yu et al. (J. Phys. Chem. B 1997, 101 (34), 6661). Transmission electron microscopic (TEM) images are determined for these gold nanorods, taken from solutions heated to various temperatures in the range of 25−160 °C. Size and shape analysis of their TEM images showed that the mean aspect ratio of the nanorods in solution decreases with increasing temperature, mostly as a result of reduction in their length. Heating the dried nanorods themselves on a TEM slide to much higher temperatures does not produce any shape changes. This suggests that the observed relative instability of the longer nanorods in the micellar solutions is attributed to the relative instability of the micelles capping the longer gold nanorods. Following the change with time of the longitudinal surface plasmon absorption band of the gold nanorods at five different temperatures, the activation ener...
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
