Thermal properties of paramagnetic radiation-induced defects in lithium orthosilicate containing breeder material

Abstract

Lithium orthosilicate (Li4SiO4) containing ceramics are currently being developed as potential solid-state candidate materials for tritium breeding in future thermonuclear fusion reactors. Under the expected operational conditions, the tritium breeding material will be exposed to the simultaneous influence of several strong energetic factors, for example, radiation, temperature, magnetic field, etc. In the present work, thermal properties of the formed and accumulated paramagnetic radiation-induced defects (containing unpaired electrons) in the Li4SiO4 pebbles with a 2.5 wt.% surplus of silicon dioxide (SiO2) were investigated after irradiation with photons of different types and energies: X-rays with an energy up to 45 keV, gamma rays with an average energy of 1.25 MeV, and bremsstrahlung with an energy up to 6 MeV. The photon-irradiated pebbles were analysed using two complementary spectroscopic methods: electron paramagnetic resonance (EPR) and thermally stimulated luminescence (TSL). Individual signals contributing to the acquired EPR spectra, TSL glow curves and spectra were distinguished, deconvoluted and simulated in order to obtain a more detailed understanding about the local structure, electron configuration, and thermal stability of the accumulated radiation-induced defects. The simulation and deconvolution data were also compared with the results, which have been acquired for the long-term neutron-irradiated pebbles from the HICU experiment (High neutron fluence Irradiation of pebble staCks for fUsion).