Abstract
Vinylated polyhedral oligomeric silsesquiox- ane (POSS-M) was prepared by the reaction of POSS containing amine groups with acrylic acid. Azobenzene liquid crystalline copolymer (LCP-POSS) was then syn- thesized with 6.0 mol% POSS-M and 94.0 mol% acrylate monomer containing azobenzene liquid crystalline moiety (Azo-M) by free-radical copolymerization. Homopolymer of Azo-M (LCP) was also synthesized under the same conditions. Their thermal properties and liquid crystallinity were characterized by Thermal gravimetric analysis (TG), differential scanning calorimetry (DSC), Wide-angle X-ray diffraction experiments (XRD) and polarized optical micrographs (POM). The results showed that LCP-POSS has higher thermal stability and glass transition tempera- ture than pure LCP due to the incorporation of the rigid cage-like POSS. Especially, LCP-POSS exhibits enantio- tropic smectic and nematic liquid crystalline behaviors, its smectic-nematic transition temperature (TSN) and nematic-isotropic transition temperature (TNI) are higher than those of pure LCP, which may promote and extend its applications on stimuli-responsive materials and devices.
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