Abstract
Thermal properties and ion mobility of (C2H6NO2)SbF4 in antimony(III) fluoride with glycine are studied by DSC, 19F NMR, and 1H NMR methods in the temperature region of 150–450 K. Dynamic processes in complex fluorides (C2H6NO2)SbF4 and (C2H6NO2)3[InF6] are juxtaposed. The NMR data reported earlier for compound (GlyH)3[InF6] are reanalyzed with some corrections. The relationship between NMR data, ion mobility, and the structure of these complexes is discussed. Possible mechanisms of ion mobility developing in complex fluorides Sb(III) and In(III) with glycine are proposed.
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