Thermal, mechanical, electrical, linear and nonlinear optical properties of a nonlinear optical l-ornithine monohydrochloride single crystal

Abstract

Optically transparent semiorganic nonlinear optical bulk single crystal of l -ornithine monohydrochloride (LOMHCL) of dimension 11×3×2 mm 3 has been grown from its aqueous solution by slow solvent evaporation technique. The grown crystal was characterized by powder X-ray diffraction to confirm the crystal structure. Investigation has been carried out to assign the vibrational frequencies of the grown crystals by Fourier transform infrared spectroscopy technique. Thermal behavior of the grown crystals was studied by thermogravimetric analysis. The second harmonic generation (SHG) efficiency of LOMHCL was determined by Kurtz and Perry powder technique. The optical absorption study confirms the suitability of the crystal for device applications. The mechanical properties of the grown crystals have been studied using Vickers microhardness tester. Dielectric and photoconductivity studies are also carried out for the grown samples.