Thermal maturity assessment study of the late Pliensbachian-early Toarcian organic-rich sediments in southern France: Grands Causses, Quercy and Pyrenean basins

Abstract

Thermal maturity of late Pliensbachian-early Toarcian organic-rich sediments in the Grands Causses (Suèges section), Quercy (Caylus section) and Pyrenean (Pont de Suert section) basins was determined through multiple parameters, including Spore Coloration Index (SCI), hydroid random reflectance (HRr) and spectral fluorescence of Tasmanites algae (λmax). The main objective of this study is to test the effectiveness and make comparisons of organic matter thermal maturity in these three sections by different techniques and particularly hydroid reflectance.For the Suèges section SCI presented a value of 3.5–4.0. HRr ranges between 0.36% and 0.47%, which corresponds to 0.45%–0.52% VReq, and shows a good correlation with SCI values. Spectral fluorescence analysis presents a λmax of 560 nm for most samples. The fluorescence spectral maximum seems to be redshifted in comparison to other thermal maturity parameters.The Caylus section exhibited SCI of 3.5–4.0. HRr ranges between 0.32% and 0.50% corresponding to 0.42%–0.54% VReq. Spectral fluorescence analysis points out a λmax of 560 nm, displaying a good correlation with SCI. When Req values determined through SCI are compared with equivalent vitrinite reflectance values determined through λmax, a redshift of the fluorescence spectrum maximum is detected.For the Pont de Suert section SCI ranges between 8.0-8.5 and 8.5–9.0. HRr varies between 0.85% and 1.18% which corresponds to 0.76%–0.98% VReq. Even though there are lower values than those obtained by SCI, VReq is reliable and acceptable to determine the thermal evolution stage. Furthermore, HRr values also present a good correlation with SCI.These data indicate that the majority of the samples from the Suèges and Caylus sections are in the immature to early mature evolution stages and Pont de Suert section samples are in late mature to early overmature evolution stages for liquid hydrocarbons generation, supporting a very similar thermal evolution for the Grands Causses and Quercy basins and an entirely different thermal history for the Pyrenean Basin. This is in accordance with the similar tectonic and sedimentary context of the Quercy and Grands Causses basins. The Pont de Suert section, located near the collision front of the Pyrenees mountains, records a more complex sedimentary and tectonic history. In addition, this study presents the first reflectance data for Jurassic hydroids, which show a good correlation with other rank parameters.