Thermal kinetics, thermodynamics, decomposition mechanism, and thermal safety performance of typical ammonium perchlorate-based molecular perovskite energetic materials

Abstract

In this work, we report the thermal kinetics, thermodynamics, and decomposition mechanism of AP-based molecular perovskite energetic materials and estimate their thermal safety performance. Typical AP-based molecular perovskite energetic materials, (H2dabco)[NH4(ClO4)3] (DAP-4), (H2pz)[NH4(ClO4)3](PAP-4), (H2mpz)[NH4(ClO4)3](PAP-M4), and (H2hpz)[NH4(ClO4)3] (PAP-H4), were synthesized and characterized. These were studied using differential scanning calorimetry (DSC). The results show that all of the obtained AP-based molecular perovskite energetic materials have higher thermal decomposition temperatures, and the peak temperatures are more than 360 °C. All follow random nucleation and growth models. Other thermodynamic parameters, such as the reaction enthalpy (ΔH), entropy change (ΔS), and Gibbs free energy (ΔG), show that they are generally thermodynamically stable. Moreover, their adiabatic induced temperatures were obtained; TD24 of DAP-4, PAP-4, PAP-M4, and PAP-H4 were 246.6, 201.2, 194.5, and 217.5 °C, respectively. This study offers an important and in-depth understanding of the thermal decomposition characteristics of AP-based molecular perovskite energetic materials and their potential applications.