Abstract

This study investigates the impact of thermal hydrolysis pretreatment (THP) on the characteristics of wastewater biosolids, methane production, anaerobic biodegradability, and recycled sidestream nitrogen loads, as a function of the sludge age of the activated sludge (AS) system through a series of BioWin simulations of 3 different process configurations at sludge ages of 5, 10, 15, 20, 30, and 60 d, with and without thermal hydrolysis. BioWin's anaerobic digester and thermal hydrolysis units were calibrated by adopting and identifying various kinetic and operational parameters from the available literature and through series of full-scale plant simulations. Thermal hydrolysis improved the hydrolysis rates of the biosolids by 181%. Improvements in anaerobic biodegradability, mainly due to the conversion of endogenous products, ranged from 14% to 67% at sludge ages of 5–15 d. At sludge ages of 20–60 d, anaerobic biodegradability improved by 59% to 186% depending on the process configuration. At sludge ages of 15–60 d, methane production was relatively stable and insensitive to the biosolids composition. Despite the increase in the recycled nitrogen load by 42% to 127%, it only constituted 13% of the influent nitrogen load. Effluent ammonia concentrations remained unchanged and effluent nitrates concentrations only increased by 1.4 to 2 mg N/L, maintaining effluent standards without additional sidestream treatment.

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