Abstract
The lattice expansion and thermal behavior of γ-irradiated unstable clathrate hydrates are explored to understand the complex physicochemical properties of clathrate hydrates. A previous study revealed that enclathrated methyl vinyl ketone molecules show a peculiar conformational change via a ketyl radical anion after γ-irradiation with an annealing process. We measured the lattice parameters of γ-irradiated binary methyl vinyl ketone + CH4, O2, and N2 hydrates at various temperatures. We observed that induced radical affects the lattice expansion behavior, and the thermal expansion coefficients of γ-irradiated hydrates highly depend on the types of secondary gaseous guest molecules.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
