Abstract
In recent years, people have higher requirements for temperature measurement with the development of optical temperature measurement. Meanwhile, the emission intensity of most fluorescent materials is quenched by thermal effects as the temperature rises, making it challenging to meet the specifications of fluorescent materials employed in the field of pyrometry. In this work, the pure phase of Yb3+/Er3+ ions co-doped Sc2W3O12 phosphor was successfully prepared. Sc2W3O12: Yb3+, Er3+ samples showed strong green emission and weak red emission. The optimal doping concentrations of Yb3+ and Er3+ ions are 0.3 and 0.02, respectively. The potential upconversion luminescence (UCL) mechanism was investigated by analyzing the UCL spectra, downshift emission spectra and power dependence spectra of Yb3+/Er3+ ions co-doped Sc2W3O12. The upconversion emission excitation path is mainly through Er3+ ions from 4I11/2 absorption photon excitation to 4F7/2 energy level, then the photons of 4F7/2 relaxes to green and red emission energy levels and returns to ground state for emitting green and red light. In addition, according to the UCL green light intensity increasing with temperature, it serves as an optical temperature sensor. The temperature sensitivity of the sample was explored in the temperature range of 298 K–673 K. This study provides new materials and ideas for non-contact temperature sensing.
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