Abstract
Field dependent polaron transport in a conjugated polymer chain is studied numerically with local thermal fluctuations taken into account. Within a dynamical evolution method, a polaron moves from the left to the right side of the polymer chain in the presence of an applied electric field. Local lattice fluctuations are assumed to occur in a random way. The local thermal fluctuations are found to be equivalent to a potential barrier for the polaron. The range of the thermally disturbed region in the molecule and the effective temperature difference resulted from asymmetric thermal absorptions determine the height of the barrier. The intra-molecule polaron mobility obeys a logarithmic law in low electric field range provided that there exist asymmetric thermal absorptions within the molecule.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
