Abstract
The molar entropy (or heat) of transport of aqueous rare earth chlorides at 0.001, 0.01 and 0.1N have been measured by the potentiometric method using the silver, silver chloride thermocell at a mean temperature of 25°C. Our results indicate that the entropy of transport of rare earth chlorides exhibits a two-series, step function type of dependence on ionic radii. Although this is not the usual S-shaped dependence on ionic radii observed in many thermodynamic and transport properties, the Soret data do seem to show that hydration of the heavier rare earth ions may be rather different from the lighter rare earth ions. The concentration dependence of the entropy of transport have also been investigated for LaCl3, SmCl3, and YbCl3. In all cases the experimental limiting slopes agree well with that predicted by theory based on the electrostatic model.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.