Abstract

Thermal reactions between a fluorocarbon ( CFx ) layer formed with C4F8 magnetomicrowave plasma and Si and SiO2 are studied by thermal desorption spectroscopy (TDS). Atomic compositions and core spectra of the CFx layer are measured by temperature-programmed X-ray photoelectron spectroscopy (TP-XPS) with concomitant desorption gas species analysis by quadrupole mass spectrometer. The TDS study reveals that the primary reaction products are SiF4 in Si and SiF4 and CO in SiO2, and F generated from the CFx layer is a primary reactive species contributing to the formation of the reaction products not only in Si but also in SiO2. The TP-XPS study reveals that the drastic decrease of F/C ratio agrees with the desorption of SiF4 and CO.

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