Abstract

Linked scanning mass spectrometry was applied to the analysis of the mixture of pyrolysis products obtained from some polyamides, pyrolyzed directly in a mass spectrometer. Collision activated decomposition spectra were obtained in order to induce a higher intensity in the metastable transition. The results indicate that linked scanning mass spectrometry provides a fast method for unambiguously assigning chemical structures through the study of molecular ions, characteristic fragmentations and comparisons of daughter and parent ions of authentic samples.

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