Thermal Degradation Kinetics Analysis of Polymer Composite Electrolyte Membranes of PEVOH and PBT Nano Fiber.

Abstract

The thermal degradation kinetics of high-performance polymer composite electrolyte membranes were investigated by thermal gravimetric analysis in this study. The novel porous polymer composite membranes were fabricated by crosslinking poly (ethylene-co-vinyl alcohol) (EVOH) with polybutylene terephthalate (PBT) nano fiber. The PBT nano-scale fiber non-woven cloth was first prepared by the electrospinning method to form a labyrinth-like structure, and the crosslinking was carried out by filtering it through a solution of EVOH and crosslinking agent triallylamine using the Porcelain Buchner funnel vacuum filtration method. The PBT–EVOH composite membranes with various crosslinking agent ratios and ethylene carbonate/dimethyl carbonate (EC/DMC) immersion times were investigated for their thermal stability and ionic conductivity. The results showed that the higher crosslinking agent content would lower the crystallinity and enhance thermal stability. The thermal degradation activation energy was dramatically increased from 125 kJ/mol to 340 kJ/mol for the 1.5% crosslinking agent content sample at 80% conversion. The triallylamine crosslinking agent was indeed effective in improving thermal degradation resistivity. The best ionic conductivity of the polymer composite membranes was exhibited at 5.04 × 10−3 S cm−1 using the optimal weight ratio of EVOH/PBT composite controlled at 1/2. On the other hand, the EC/DMC immersion time was more effective in controlling the Rb value, thus the ionic conductivity of the membranes. A higher immersion time, such as 48 h, not only gave higher conductivity data but also provided more stable results. The triallylamine crosslinking agent improved the membrane ionic conductivity by about 22%.