Abstract
Abstract The thermal decomposition reaction of halogenopentaammineruthenium(III) complexes was studied by the techniques of thermogravimetry, differential thermal analysis and evolved gas analysis. The complexes were dissociated by two different mechanisms:(a) those in which the Ru(III) was reduced by halide ion; and (b) those in which the Ru(III) was reduced by ammonia molecule. Which mechanism is preferably selected for a thermal decomposition reaction, it seems to be determined by the composition of ligands in the complexes.
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