Abstract
Accurate temperature measurements are always difficult to obtain in chemical kinetics experiments. It is possible to evaluate the difference between the actual temperature and the measured temperature using calibration techniques. The initial rates of formation of the primary products in the thermal decomposition of propane were measured. As the mechanistic model of the pyrolysis of propane is well known, the corresponding initial rates of product formation were calculated and by comparison the actual temperature in this plug flow reactor was deduced.
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