Abstract
Shock-tube studies at the National Institute of Standards and Technology (NIST) and the University of Illinois at Chicago (UIC) have been used to examine the decomposition of 1-pentyl radicals in argon between (833–1130)K and (100–5000)kPa. High pressure limiting values of the product branching ratios appear to be approached at the highest pressures studied. Results agree well with a ‘best-fit’ model previously developed [1] and are consistent with an energy transfer value 〈ΔEdown〉=(675±100)cm−1 at 1000K.
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