Abstract
The combustion of two kinds of biomass and sewage sludge was studied. The biomass fuels were wood biomass (pellets) and agriculture biomass (oat). The sewage sludge came from waste water treatment plant. The biomass and sludge percentage in blends with coal were 10 %. The studied materials were characterised in terms of their proximate and ultimate analysis and calorific value. The composition of the ash of the studied fuels was also carried out. The behaviour of studied fuels was investigated by thermogravimetric analysis (TG, DTG and DTA). The samples were heated from an ambient temperature up to 1,000 °C at a constant three rates: 10, 40 and 100 °C min−1 in 40 mL min−1 air flow. TG, DTG and DTA analysis showed differences between coal, biomass fuels and sewage sludge. 10 % addition of studied fuels to the mixture with coal changed its combustion profile in the case of sewage sludge addition. The combustion characteristics of fuel mixtures showed, respectively, qualitative summarise behaviour based on single fuels. Evolved gaseous products from the decomposition of studied samples were identified. This study showed that thermogravimetric analysis connected with mass spectrometry is useful techniques to investigate the combustion and co-combustion of biomass fuels, and sewage sludge, together with coal. Non-isothermal kinetic analysis was used to evaluate the Arrhenius activation energy and the pre-exponential factor. The kinetic parameters were calculated using Kissinger–Akahira–Sunose model.
Highlights
The development of industry and increasing production, thereby increasing the demand for energy, contributes to the use of energy sources other than conventional ones
This study showed that thermogravimetric analysis connected with mass spectrometry is useful techniques to investigate the combustion and co-combustion of biomass fuels, and sewage sludge, together with coal
The nitrogen content of sewage sludge is the highest among the investigated fuels, so a high Nitrogen oxides (NOx) emission could be expected. As for ash, this is about thirty times higher for sewage sludge than for oat or wood biomass. When it comes to calorific values, the energy content is widely higher for biomass than for sewage sludge, as can be seen from the high heat values (HHV)
Summary
The development of industry and increasing production, thereby increasing the demand for energy, contributes to the use of energy sources other than conventional ones (coal or natural gas). TG, DTG and DTA analysis showed differences between coal, biomass fuels and sewage sludge. 10 % addition of studied fuels to the mixture with coal changed its combustion profile in the case of sewage sludge addition.
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