Thermal characteristics of cementitious building materials with carbon and PCM for improved heat storage performance

Abstract

The thermal properties of cementitious building materials were analyzed by integrating phase change materials (PCMs) and carbon materials to improve their heat storage performance. Four types of carbon materials, namely activated carbon (AC), carbon nanotubes (CNT), exfoliated graphite nanoplatelets (xGnPs), and graphene, were dispersed in PCMs and impregnated into artificial lightweight aggregates via vacuum impregnation to create cement building materials. Various parameters including compressive strength, differential scanning calorimetry (DSC), hydration heat, thermal conductivity, and dynamic heat transfer were evaluated According to the results, the thermal conductivity of PCM was significantly improved by incorporating carbon materials, and the specimen with CNT showed a result of 0.8386 W/m∙K, which is about 20 % higher than that of the specimen without carbon materials. Although the compressive strength decreased with the addition of PCMs, it remained above 20 MPa, thereby ensuring structural integrity. In the dynamic heat transfer test, the carbon/PCM specimen maintained a higher temperature during heat dissipation. It showed a high peak temperature and a time delay of about 2.5 hours during free cooling. The results showed that integrating PCMs and carbon materials into cementitious building materials could effectively improve their thermal performance, potentially saving building energy.