Abstract
Four new complex compounds were prepared by reaction of zinc carboxylate and methyl-3-pyridyl carbamate. The synthesized complex compounds of the general formula (RCOO)2ZnL2 (RCOO-= HCOO- (form), CH3COO- (ac), CH3CH2CH2COO- (but), (CH3)2CHCOO- (isobut), L= methyl-3-pyridyl carbamate (mpc)) were characterized by chemical analysis, IR spectroscopy and studied by methods of thermal analysis (TG/DTG, DTA). CH2O, CO2, (CH3)2CO, (C3H7)2CO were found as volatile products of thermal decomposition. ZnO was found as final product of thermal decomposition of the prepared complexes heated up to 700°C. Mass spectroscopy, X-ray powder diffraction method, IR spectra and chemical analysis were used for the determination of the thermal decomposition products.
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