Abstract

The thermal decomposition of two dinitrogen complexes of iron with EDTA and CDTA have been studied using DTA and TG techniques. Intermediate products in the decomposition processes were characterized by IR spectroscopy. For both compounds the loss of dinitrogen occurs at ca. 230°C, and it is accompanied by the disappearance of the ν NN band in the IR spectra of the intermediate products. Na 2O and FeO are obtained as final products at 900°C.

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