Thermal behaviour of composites

Abstract

The behaviour of composite materials is often sensitive to changes in temperature. This arises for two main reasons. Firstly, the response of the matrix to an applied load is temperature-dependent and, secondly, changes in temperature can cause internal stresses to be set up as a result of differential thermal contraction and expansion of the two constituents. These stresses affect the thermal expansivity (expansion coefficient) of the composite. Furthermore, significant stresses are normally present in the material at ambient temperatures, since it has in most cases been cooled at the end of the fabrication process. Changes in internal stress state on altering the temperature can be substantial and may strongly influence the response of the material to an applied load. Creep behaviour is affected by this, particularly under thermal cycling conditions. Finally, the thermal conductivity of composite materials is of interest, since many applications and processing procedures involve heat flow of some type. This property can be predicted from the conductivities of the constituents, although the situation may be complicated by poor thermal contact across the interfaces. Thermal expansion and thermal stresses Thermal stresses and strains Data for the thermal expansion coefficients (a) of matrices and reinforcements, as a function of temperature, are shown in Fig. 10.1. Polymers and metals generally expand more than ceramics. It can be seen that the differences in expansivity between fibre and matrix are large in many cases.