Abstract
The layered ion-exchangers γ-zirconium phosphate and γ-zirconium phosphate containing intercalated diamines, obtained by exchanging zinc ions, have been synthesized and characterized. Zinc ions are able to form coordination compounds between the layers of the host matrix and consequently form zinc complexes formed in situ. The zinc ions uptake, the thermal behavior and the structural characterization of the compounds obtained have also been examined. The thermal stability and X-ray spectra of these compounds depend on the type of isomeric diamine precursor. The zinc fully exchanged γ-zirconium phosphate is able to form ZnS particles in the host matrix. The X-ray spectra of this obtained material matched those of the initial γ-zirconium phosphate precursor.
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