Thermal and structural properties of low-fluence irradiated graphite

Abstract

The release of Wigner energy from graphite irradiated by fast neutrons at a TRIGA Mark II research reactor has been studied by differential scanning calorimetry and simultaneous differential scanning calorimetry / synchrotron powder X-ray diffraction between 25 and 725 °C at a heating rate of 10 °C min −1. The graphite, having been subject to a fast-neutron fluence from 5.67 × 10 20 to 1.13 × 10 22 n m −2 at a fast-neutron flux ( E > 0.1 MeV) of 7.88 × 10 16 n m −2 s −1 and at temperatures not exceeding 100 °C, exhibits Wigner energies ranging from 1.2 to 21.8 J g −1 and a Wigner energy accumulation rate of 1.9 × 10 −21 J g −1 n −1 m 2. The differential–scanning–calorimeter curves exhibit, in addition to the well known peak at ∼200 °C, a pronounced fine structure consisting of additional peaks at ∼150, ∼230, and ∼280 °C. These peaks correspond to activation energies of 1.31, 1.47, 1.57, and 1.72 eV, respectively. Crystal structure of the samples is intact. The dependence of the c lattice parameter on temperature between 25 and 725 °C as determined by Rietveld refinement leads to the expected microscopic thermal expansion coefficient along the c axis of ∼26 × 10 −6 °C −1. At 200 °C, coinciding with the maximum in the differential–scanning–calorimeter curves, no measurable changes in the rate of thermal expansion have been detected – unlike its decrease previously seen in more highly irradiated graphite.