Abstract
Abstract One-pot reaction among [(Cp)2Mo2(CO)6], elemental sulfur, and dimethyl acetylenedicarboxylate (DMAD) affords several types of dinuclear molybdenadithiolene complexes. The thermal reaction gives [(Cp)(CO)2Mo{μ-S2C2(CO2Me)2}2Mo(Cp)] (2), while the photoreaction gives mainly isomeric [(Cp)Mo(CO){μ-S2C2(CO2Me)2}2Mo(CO)(Cp)] (3). The former dicarbonylmolybdenum complex easily undergoes decarbonylation, while the latter is thermally stable.
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