Thermal and optical properties of poly(methyl methacrylate)/calcium carbonate nanocomposite

Abstract

The study deals with thermal and optical properties of poly(methyl methacrylate) (PMMA) containing 2wt% calcium carbonate (CaCO3) nanofiller. It was found that the thermal conductivity increases with increasing temperatures, due to thermal activation of the phonons in the PMMA/CaCO3 nanocomposite. This enhancement in the thermal conduction is mainly attributed to the heat transferred by lattice vibrations as major contributors and electrons as minor contributors during thermal conduction. The optical properties were investigated as a function of wavelength and photon energy of UV radiation. The optical results obtained were analysed in terms of absorption formula for noncrystalline materials. It was found that the measured optical energy gap for the pure PMMA is greater than the PMMA/CaCO3 nanocomposite. The width of the energy tails of the localised states was calculated. Adding CaCO3 nanofiller into PMMA matrix may cause the localised states of different colour centres to overlap and extend in the mobility gap. This overlap may give an evidence for decreasing energy gap when adding CaCO3 nanofiller in the polymer matrix.