Thermal and mechanical characterization of poly(vinyl chloride)-b-poly(butyl acrylate)-b-poly(vinyl chloride) obtained by single electron transfer – degenerative chain transfer living radical polymerization in water

Abstract

This work reports the synthesis of several copolymers of poly(vinyl chloride)-b-poly( n-butyl acrylate)-b-Poly(vinyl chloride) prepared by single electron transfer/degenerative chain transfer mediated living radical polymerization (SET-DTLRP) in a two step process: first, a bifunctional macroinitiator of α,ω-di(iodo)poly(butyl acrylate) [α,ω-di(iodo)PBA] was synthesized by SET-DTLRP in water at 30 °C. The obtained macroinitiator was further reinitiated also by SET-DTLRP leading to the formation of the desired product. Several copolymers were synthesized in a 5L pilot reactor with different molecular weights and relative amounts of PBA and PVC. The possibility of synthesizing flexible materials made of PVC without using normal free plasticizes is extremely important for the industry. After processing the materials in a two-roll mill laboratorial equipment, the block copolymers were characterized concerning thermal and mechanical. The materials characterized in this study were prepared in a 5L pilot reactor under similar conditions to be used in industrial scale.