Thermal and magnetic dual-responsive switchable device with superhydrophilicity/underwater superoleophobicity and excellent targeted oil–water separation performance

Abstract

In view of the increasingly serious problem of oil–water separation, it is a convenient and practical method to introduce a hydrogel coating on the surface of materials to make super-wetting materials. Nowadays, researchers of super-wetting materials pay more attention to the research and development of responsive materials. Here, a thermal and magnetic dual-responsive superhydrophilicity/underwater superoleophobicity switchable device (Fe3O4@PNIPAM-Cu) was simply fabricated using the Fe3O4 nanoparticles, poly-N-isopropylacrylamide (PNIPAM) hydrogel as the functional coating and copper foam as the skeleton through a one-step solution immersion method. The separation efficiency of the benzene-water mixture of this dual-responsive device can reach up to 99.98%. Even after 10 separation cycles, it maintained an efficiency of more than 99.90%. At temperatures above ~34°C, the device can stop oil–water separation. The experiments presented here demonstrate this dual-responsive device possesses excellent superhydrophilicity/underwater superoleophobicity, thermal-responsive property and magnetic navigation function.