Thermal and ignition properties of hexanitrostilbene (HNS) microspheres prepared by droplet microfluidics

Abstract

HNS-IV (Hexanitrostilbene-IV) is the main charge of the exploding foil initiators (EFI), and the microstructure of the HNS will directly affect its density, flowability, sensitivity, and stability. HNS microspheres were prepared using droplet microfluidics, and the particle size, morphology, specific surface area, thermal performance, and ignition threshold of the HNS microspheres were characterized and tested. The results shown that the prepared HNS microspheres have high sphericity, with an average particle size of 20.52 μm (coefficient of variation less than 0.2), and a specific surface area of 21.62 m2/g (6.87 m2/g higher than the raw material). Without changing the crystal structure and thermal stability of HNS-IV, this method significantly enhances the sensitivity of HNS-IV to short pulses and reduces the ignition threshold of the slapper detonator to below 1000 V. This will contribute to the miniaturization and low cost of EFI.