Abstract
The thermogravimetric analysis (TGA) and electron paramagnetic resonance (EPR) studies of powder and single crystals of bis(acesulfamato)tetraaquazinc(II), Zn(acs) 2(H 2O) 4, a novel coordination compound, are carried out. Previously synthesized bis(acesulfamato) tetraaquamanganese(II), Mn(acs) 2(H 2O) 4, is included into the host in trace amount as a paramagnetic probe for EPR analysis. Single crystal EPR spectra at room temperature are resolved and discussed. Low temperature EPR spectra down to 90 K do not show remarkable change. At higher temperatures, however, the TGA and EPR spectra show changes around 335 K and 395 K; the causes and the mechanisms of changes are discussed.
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More From: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
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