Abstract
Novel methylhydrazine and methylhydrazinium chloride complexes of copper in various oxidation states (1, 4 3 , 2) have been prepared and characterised by elemental analyses and magnetic data. The thermal decomposition of these complexes was studied by simultaneous DTA, TG and DTG. The complex Cu(II)Cl 2(NH 2NH 2CH 3Cl) decomposes on heating with reduction to Cu(I)Cl. Significantly the complex Cu 3(2I, II)Cl 6(NH 2NH 2CH 3) 2 on heating disproportionates as follows 3Cu( 4 3 ) → 2 Cu(I) + Cu(II).
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