Abstract

The behaviour of graphite intercalation compounds with FeCl 3 (1st and 2nd stages) was characterized by a number of thermal analysis methods up to 800 K. The compounds were shown to undergo reversible solid phase transformations and were subjected to thermal destruction. Temperature, kinetic, and energy characteristics of thermally stimulated processes in the compounds under different ambient conditions are given. An assumption is made about a pyrolysis mechanism for different temperature ranges. A conclusion is drawn about the slightly higher thermal stability of the 2nd stage as compared with the 1st stage graphite intercalation compounds with FeCl 3.

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