Abstract

Abstract Two types of thermal effects, caused by substitutions (Ca2+↔ Na+, ↔ CO3 2-, SO4 2-, OH-↔ F-) in synthetic precipitated apatites as well as by sorption of Cd2+, Zn2+, and Cr3+ ions from the solutions were studied by TG/DTA, XRD and FTIR analysis. The temperatures of exothermic effect at 330-340°C and of decomposition of carbonate and sulfate apatites at 650-950°C were shown to depend on the substitutions in the apatite structure.

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