Abstract

Marine sediment preserves a useful archive for contaminants and other properties that associate with particles. However, biomixing of sediments can smear the record on a scale of years to thousands of years, depending on sedimentation rate and on the depth and vigour of mixing within a particular sediment. Where such mixing occurs, dates can no longer be associated with discrete sediment depths. Nevertheless, much can still be learned from biomixed profiles, provided that mixing is accounted for. With no modelling at all, it is possible to calculate an inventory of a contaminant at a site and a maximum possible sedimentation rate, and to determine whether the contaminant has increased or decreased over time. Radiodating the core with 210Pb permits the estimation of sedimentation and mixing rates, which can be combined with the surface contaminant concentration to estimate an approximate flux of the contaminant. Numerical models that incorporate sedimentation and mixing rates (determined using 210Pb and other transient signals with known deposition histories) can provide the basis to propose plausible histories for contaminant fluxes.

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