Theory of thin-vapor-layer linear-optical properties: The case of quenching of atomic polarization upon collisions of atoms with dielectric walls

Abstract

Hot alkali metal vapors enclosed in submicron spectroscopic cells provide an ideal system for fundamental studies of the atom-wall and atom-light interactions at the nanoscale. Here, we propose an approach for calculating the eigenmodes of a thin vapor layer beyond the limitations of the first-order perturbation theory in optical density for the case of quenching of atomic polarization upon collisions of atoms with dielectric walls. We show that higher-order optical density corrections lead to a remarkable density-dependent blueshift and deformation of the spectral line shapes of reflection, transmission, and absorption. We also demonstrate that the eigenmodes of the thin vapor layer can be calculated independently of the choice of optical boundary conditions. This greatly extends the applicability of the constructed theory for the development of miniature atomic sensors.