Abstract
The effect of radiofrequency pulses in nuclear quadrupole resonance (NQR) spectroscopy is examined. The description is different from that needed in nuclear magnetic resonance (NMR) spectroscopy. In particular, both rotating and counter-rotating radiofrequency field components are retained. Pulses in NQR spectroscopy are selective and cause transitions between two pairs of levels (±M) → ±(M + 1), other transitions are not normally excited. The formulation of pulses is then described for any spin I by two 2 × 2 rotation matrices, one causing an M → M + 1 transition and the other causing a - (M + 1) → -M transition. Calculations on resonance for spins with an axially symmetric nuclear quadrupole for up to three pulses are presented for spins I = 1 and I = 3/2. The results agree with the work of Reddy, R. and Narasimhan, P. T., 1991, Molec. Phys., 72, 491, in the appropriate limits.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
