Abstract
A theoretical model of energy transfer between Si nanocrystals and Er 3+ ions in SiO 2 matrix is presented. The mechanism, based on the Coulomb interaction between carriers confined in nanocrystal and f-electrons of erbium ions, is considered to be responsible for the excitation and quenching of the 1.55 μ m luminescence, and particularly for its recently discovered nanosecond dynamics. It has been shown that phonon-assisted intraband transition of a confined carrier can give rise to erbium transition into the first excited state with characteristic time being in the nanosecond range.
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