Abstract

The object of this paper is to lay the foundations of the Theory of Dilute Macromolecular Solutions in a unified, simplified, and yet rigorous manner. It also aims to acquaint chemists and physicists with a field of rapidly increasing significance, in view of possible applications to biophysics (and biochemistry). The Introduction gives a brief outline of the historical development of macromolecular solution theory. Roughly, one can distinguish between (a) lattice- and (b) gas-type theories, just as in the theory of liquids. The former, because of their apparent simplicity, have enjoyed great popularity for a long time among polymer chemists. However, lately, again just as for liquids, the gas-type approach has been proven to be more fundamental.

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